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Aromatic chloroosmacyclopentatrienes

National Science Review, ISSN: 2053-714X, Vol: 10, Issue: 3, Page: nwac237
2023
  • 5
    Citations
  • 0
    Usage
  • 0
    Captures
  • 2
    Mentions
  • 0
    Social Media
Metric Options:   Counts1 Year3 Year

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  • Citations
    5
  • Mentions
    2
    • News Mentions
      1
      • News
        1
    • References
      1
      • Wikipedia
        1

Most Recent News

Synthesis of the first aromatic chloroosmacyclopentatriene featuring a unique M=ClC bond

image: The bonding types between transition metals and chloride (I), chlorocarbons (II-IV). view more  Credit: ©Science China Press This study is led by Dr. Jiangxi Chen

Article Description

Aromatic metallacycles are of considerable current interest. Reported aromatic metallacycles are mainly those with carbon, nitrogen, oxygen and sulfur. In this work, we report the synthesis and characterization of aromatic chloroosmacyclopentatrienes, which represent the first structurally confirmed metallaaromatic with a chlorine atom in its framework. Single-crystal X-ray diffraction studies show that these planar chloroosmacyclopentatrienes possess a very short Os–ClC distance suggesting M=ClC bond character.

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