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Structural study of stage-1 cesium graphite at high temperatures

Physical Review B, ISSN: 0163-1829, Vol: 22, Issue: 12, Page: 6308-6318
1980
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  • Citations
    23
    • Citation Indexes
      23

Article Description

New x-ray-diffraction results on the high-temperature structure of state-1 Cs graphite as a function of sample temperature and Cs-vapor pressure are presented. It is shown that the dominant factor in determining the high-temperature structure is the concentration of Cs atoms. An order-disorder transition occurs when the saturated compound C8Cs decomposes. The decomposition occurs in two steps. The sample first transforms from the 300-K ordered phase with αβγ stacking to an unstable ordered phase with αβ stacking. Then the sample undergoes an order-disorder transition to a phase with "liquidlike" planar structure. Also presented is evidence for the existence of an αβγδ stacking sequence in stage-1 Cs graphite at 300 K. © 1980 The American Physical Society.

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