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Anomalous Saturated-Absorption Pressure Shifts in CO2

Physical Review Letters, ISSN: 0031-9007, Vol: 53, Issue: 15, Page: 1437-1440
1984
  • 16
    Citations
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  • 2
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Metrics Details

  • Citations
    16
    • Citation Indexes
      16
  • Captures
    2

Article Description

Pressure shifts of the standing-wave saturated resonance have been measured in the 9-and 10-m P and R lasing transitions of CO2 with a heterodyne spectroscopic technique. At low pressures (100 m Torr) the measured shifts for four different isotopes were all blue, instead of red as predicted by semiclassical theory. Measurements at higher (> 1 Torr) pressures revealed red shifts. Perturber-gas data showed blue shifts for heavier perturber atoms or molecules, red shifts for He and H2. © 1984 The American Physical Society.

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