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Poly[(-4,4′-bipyridine)(-naphthalene-1,4-dicarboxyl-ato)manganese(II) ]

Acta Crystallographica Section E: Structure Reports Online, ISSN: 1600-5368, Vol: 65, Issue: 4, Page: m421
2009
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Article Description

In the crystal structure of the title compound, [Mn(CH O)(CHN)] n , the Mn atoms are each coordinated by four O atoms of naphthalene-1,4-dicarboxyl-ate anions and two N atoms of two symmetry-related 4,4′-bipyridine ligands within a strongly distorted octa-hedra. Two of the O atoms originate from one naphthalene-1,4-dicarboxyl-ate anion, whereas the remaining two O atoms derive from two symmetry-equivalent naphthalene-1,4-dicarboxyl-ate anions. Two Mn atoms are connected via the anions into dimers, which are further linked by the anions and the N-donor ligands into a three-dimensional coordination network.

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