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Catena-Poly[[(8-Aminoquinoline)cobalt(II)]-di-μ-Azido]

IUCrData, ISSN: 2414-3146, Vol: 9, Issue: Pt 9, Page: x240849
2024
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Article Description

The title coordination polymer, [Co(N3)2 (C9H8N2)]n, was synthesized solvothermally. The CoII atom exhibits a distorted octahedral [CoN6] coordination geometry with a bidentate 8-Aminoquinoline ligand and four azide ligands. Bridging azide ligands result in chains extending along [100]. N-H⋯N hydrogen bonds join the chains to give an extended structure with sheets parallel to (002).

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