Tuning metal surface diffusion on diblock copolymer films
Journal of Vacuum Science and Technology A: Vacuum, Surfaces and Films, ISSN: 0734-2101, Vol: 25, Issue: 4, Page: 1048-1051
2007
- 20Citations
- 6Captures
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Article Description
The authors have studied the effect of predeposition electron exposure on the diffusion behavior of silver evaporated on a diblock copolymer template. Unexposed regions display a highly selective adsorption of Ag clusters on the polystyrene domains. Exposure to the electron beam modifies the surface diffusion constants on each polymer block and produces a trend of smaller mean particle sizes with increased dose. While there is a loss of selectivity in this system upon exposure, alternative diblock chemistries or exposure procedures could enable one to engineer the selectivity of desired materials on polymer films. © 2007 American Vacuum Society.
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