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C -C hydrocarbon release in the preparation of SiF through Na SiF pyrolysis

Inorganic Materials, ISSN: 0020-1685, Vol: 48, Issue: 1, Page: 7-9
2012
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Hydrocarbon impurities in silicon tetrafluoride originate from the sodium hexafluorosilicate used as a precursor for the preparation of SiF through the thermal decomposition of Na SiF . We have studied the fraction of C -C hydrocarbons released as a function of temperature during the thermal decomposition of sodium hexafluorosilicate. The lighter hydrocarbons-methane, ethane, and ethylene-are shown to be released at lower temperatures. One source of hydrocarbon impurities in sodium hexafluorosilicate is the sodium carbonate used to prepare it. © 2012 Pleiades Publishing, Ltd.

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