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Crystal structure of bis-Isonicotinoyl hydrazone of 2,5-diformylpyrrole

Journal of Structural Chemistry, ISSN: 0022-4766, Vol: 54, Issue: 3, Page: 592-597
2013
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Article Description

bis-Isonicotinoyl hydrazone of 2,5-diformylpyrrole existing in the crystal in the form of a tetrahydrate of the hydrazone tautomeric form is synthesized and its structure is described. In the crystal, an infinite three-dimensional network of hydrogen bonds is formed by hydrazone molecules. The neighboring hydrazone molecules are bonded by intermolecular π stacking interactions. A quantum chemical calculation of the geometry and total energy of possible tautomers in vacuum and an aqueous solution is performed. © 2013 Pleiades Publishing, Ltd.

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