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FT-IR, H NMR, C NMR and X-ray crystallographic structure determination of 4-nitro-benzenesulfonic acid 2,4-bis-(1-phenyl-ethyl)-naphthalen-1-yl ester

Journal of Structural Chemistry, ISSN: 1573-8779, Vol: 56, Issue: 2, Page: 392-395
2015
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Article Description

The title compound CHNOS belongs to the monoclinic system, space group P2/c with a = 14.4530(5) Å, b = 13.9185(5) Å, c = 13.5714(4) Å, α = γ = 90°, β = 87.174(3), V = 2726.76(16) Å, Z = 4, D = 1.310 g/cm, F(000) = 1128, R = 0.053 and wR = 0.133, S = 1.03, T = 296 K. In the title compound, the naphthalene unit is planar (r.m.s. deviation = 0.0227 Å). The dihedral angle between the naphthalene unit and nitro-benzenesulfonic acid, 2-phenyl-ethyl and 4-phenyl-ethyl are 49.68(05)°, 82.96(06)°, and 81.94(07)°respectively. The structure is stabilized by intra- and intermolecular C-H...O hydrogen bonds.

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