Structure of a trinuclear μ-vinylidene cluster CpMnFePt(μ-C=CHPh)(PPh)(CO)
Journal of Structural Chemistry, ISSN: 0022-4766, Vol: 58, Issue: 3, Page: 600-602
2017
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Article Description
The single crystal X-ray diffraction study of the heterometallic cluster CpMnFePt(μ-C=CHPh)(PPh)(CO) is performed. The crystallographic characteristics are as follows: a = 32.356(15) Å, b = 11.754(5) Å, c = 20.114(9) Å, β = 115.707(6)°, V = 6893(5) Å, space group C2/c, Z = 8, d = 1.741 g/cm. The cluster molecule contains a bridging phenylvinylidene ligand coordinated to a metallic core in the form of a Mn–Fe–Pt chain (the Mn–Fe and Fe–Pt bond lengths are 2.6768(14) Å and 2.6280(11) Å respectively and the Mn⋯Pt distance is 3.6425(19) Å).
Bibliographic Details
http://www.scopus.com/inward/record.url?partnerID=HzOxMe3b&scp=85021247061&origin=inward; http://dx.doi.org/10.1134/s0022476617030234; http://link.springer.com/10.1134/S0022476617030234; http://link.springer.com/content/pdf/10.1134/S0022476617030234.pdf; http://link.springer.com/article/10.1134/S0022476617030234/fulltext.html; https://dx.doi.org/10.1134/s0022476617030234; https://link.springer.com/article/10.1134/S0022476617030234
Pleiades Publishing Ltd
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