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Vibrational spectrum and structural features of the high-temperature superconductor YBaCuO

Russian Journal of Inorganic Chemistry, ISSN: 0036-0236, Vol: 53, Issue: 6, Page: 918-927
2008
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Article Description

The structure of YBaCuO has been represented as consisting of molecular ions CuO and described in space group P4m2. This structure provides a satisfactory interpretation of IR-and Raman-active bands. The calculated isotope shifts of the bands induced by the substitution of O for O are well consistent with the measured shifts. A possible mechanism of the motion of electron pairs is suggested. © 2008 Pleiades Publishing, Ltd.

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