A propanediamine-bridged dinuclear iron(III) complex: Synthesis, X-ray analyses, spectral studies, and magnetic properties
Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya, ISSN: 1070-3284, Vol: 37, Issue: 5, Page: 377-381
2011
- 3Citations
- 6Captures
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Article Description
A new propylenediamine-bridged diunclear complex formulated as [Fe (Salpn)] (I) (pn = 1,2-propylenediamine, H Salpn = N,N′ diamine Schiff base) has been prepared from the template synthesis by the reaction of 1,2-propylenediamine with salicylaldehyde in the presence of the iron(III) salt. The metal centers adopt a slightly distorted octahedral geometry, and the Salpn ligands act in both bridging and chelating modes to form a dinuclear complex with the six-membered chelate rings. The magnetic susceptibility investigation for I indicates the presence of very weak antiferromagnetic coupling between the Fe cations through the propylenediamine bridge. © 2011 Pleiades Publishing, Ltd.
Bibliographic Details
http://www.scopus.com/inward/record.url?partnerID=HzOxMe3b&scp=79958077919&origin=inward; http://dx.doi.org/10.1134/s1070328411040038; http://link.springer.com/10.1134/S1070328411040038; http://link.springer.com/content/pdf/10.1134/S1070328411040038; http://link.springer.com/content/pdf/10.1134/S1070328411040038.pdf; http://link.springer.com/article/10.1134/S1070328411040038/fulltext.html; http://www.springerlink.com/index/pdf/10.1134/S1070328411040038; http://www.springerlink.com/index/10.1134/S1070328411040038; https://dx.doi.org/10.1134/s1070328411040038; https://link.springer.com/article/10.1134/S1070328411040038
Pleiades Publishing Ltd
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