Neutral and monocationic dinuclear (carbonyl)(cyclopentadienyl) (phenylchalcogenate) iron complexes of the general formulas [(RC H)Fe(CO)EPh] and [(RCH )Fe(CO)EPh]PF (E = S or Te; R = H or Me): Synthesis, molecular structures, and EPR spectra
Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya, ISSN: 1070-3284, Vol: 39, Issue: 12, Page: 822-828
2013
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Article Description
Heating of the compounds (RCH)Fe(CO) TePh (R = H (I) and Me (II)) in heptane afforded the dinuclear complexes [(RCH)Fe(CO)TePh] (III and IV, respectively). By oxidation with FcPF, these complexes were transformed into the paramagnetic cationic complexes [(RC H)Fe(CO)TePh]PF (Vand VI, respectively). Structures III-V and [(CH)Fe(CO)SPh] PF (VII) were characterized by X-ray diffraction. © Pleiades Publishing, Ltd., 2013.
Bibliographic Details
http://www.scopus.com/inward/record.url?partnerID=HzOxMe3b&scp=84893010070&origin=inward; http://dx.doi.org/10.1134/s1070328413120038; http://link.springer.com/10.1134/S1070328413120038; http://link.springer.com/content/pdf/10.1134/S1070328413120038; http://link.springer.com/content/pdf/10.1134/S1070328413120038.pdf; http://link.springer.com/article/10.1134/S1070328413120038/fulltext.html; https://dx.doi.org/10.1134/s1070328413120038; https://link.springer.com/article/10.1134/S1070328413120038
Pleiades Publishing Ltd
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