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Synthesis and Bromofluorination of Bis(methallyloxy)benzene and Bis(methallyloxy)biphenyl

Russian Journal of Organic Chemistry, ISSN: 1608-3393, Vol: 59, Issue: 9, Page: 1641-1643
2023
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Article Description

Abstract: The synthesis of new symmetrical 1,4-bis(methallyloxy)benzene and 4,4′-bis(methallyloxy)bi­phenyl and their bromofluorination with N-bromosuccinimide (NBS) and triethylamine trihydrofluoride (EtN·3HF) have been described. The bromofluorination afforded exclusively the corresponding Markovnikov adducts with the fluorine atoms attached to the tertiary carbon atoms. The new compounds were characterized by IR, H, C, and F NMR, and high-resolution mass spectra.

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