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Iron-based catalytic systems in atom-transfer controlled-radical-polymerization processes

Polymer Science - Series C, ISSN: 1555-614X, Vol: 57, Issue: 1, Page: 32-64
2015
  • 10
    Citations
  • 0
    Usage
  • 5
    Captures
  • 0
    Mentions
  • 0
    Social Media
Metric Options:   Counts1 Year3 Year

Metrics Details

  • Citations
    10
    • Citation Indexes
      10
  • Captures
    5

Article Description

The literature data about the use of catalytic systems and compositions based on iron and its complexes for the controlled synthesis of polymers via the atom-tansfer mechanism are generalized and analyzed. The effects of the oxidation number of a metal atom, the ligand environment, the structure of a radical initiator, the activating additives, and other factors on the molecular-weight characteristics of the polymers and the kinetics of vinyl polymerization are considered.

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