Hybrid crystals of calcium carbonate and amino acids
Japanese journal of applied physics, ISSN: 0021-4922, Vol: 39, Issue: 10 B
2000
- 11Citations
- 5Captures
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Article Description
We have investigated the effects of amino acids on the crystallization of calcium carbonate (CaCO), and the reactivity between amino acids and CaCO. Noncharged-polar and acidic amino acids are highly incorporated into CaCO and stabilize cauliflower-like grains composed of vaterite which is thermodynamically unstable in the CaCO polymorphs. Amino acids in the hybrid CaCO form radicals different from those in crystalline amino acids by X-ray irradiation. The results imply that the hybrid carbonate can provide a reaction field for organic synthesis. We also propose models for the bond between amino acids and CaCO using semiempirical approximation procedures.
Bibliographic Details
http://www.scopus.com/inward/record.url?partnerID=HzOxMe3b&scp=0034292053&origin=inward; http://dx.doi.org/10.1143/jjap.39.l1071; https://iopscience.iop.org/article/10.1143/JJAP.39.L1071; https://dx.doi.org/10.1143/jjap.39.l1071; https://validate.perfdrive.com/9730847aceed30627ebd520e46ee70b2/?ssa=68843670-8791-437f-9294-a0a9ad27d873&ssb=62794242820&ssc=https%3A%2F%2Fiopscience.iop.org%2Farticle%2F10.1143%2FJJAP.39.L1071&ssi=157e99b6-cnvj-4ec3-9219-e168710f8f66&ssk=botmanager_support@radware.com&ssm=935421711698394501685172850857515001&ssn=26b92a615f0315fa8ed35deb0ca07338473ee3e449d9-548a-4c5b-96e82d&sso=8674acaf-f497241c935f1448731523fe7d93fcda11dbeecc22c705d0&ssp=12014797661732168213173294013935724&ssq=58648318811424232563226405700524873120606&ssr=NTIuMy4yMTcuMjU0&sst=com.plumanalytics&ssu=&ssv=&ssw=&ssx=eyJ1em14IjoiN2Y5MDAwZWUyZGRiODMtZjY4Ny00ZGY4LTliMTMtNDQ0OWIzZDhjZjczMTEtMTczMjEyNjQwNTI2Njg2MTcwOTAyNS03OTRkYjFiNTFiZmE4OGJjMTY4NDkwIiwiX191em1mIjoiN2Y2MDAwMmU0NDlkM2ItMDIzYi00NzI2LWIyOGEtZDQ0NTE5NTc2YTQ1MTczMjEyNjQwNTI2Njg2MTcwOTAyNS0yMzBhMTA0NDRiYjNlZTE5MTY4NDk2IiwicmQiOiJpb3Aub3JnIn0=
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