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Doped Superior Garnet Electrolyte Toward All-Solid-State Li Metal Batteries

SSRN, ISSN: 1556-5068
2022
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  • Usage
    206
    • Abstract Views
      181
    • Downloads
      25

Article Description

LiLaZrO(LLZO) garnets are one of the most promising solid electrolytes for next generation all-solid-state Li metal batteries due to their high ionic conductivities, chemical stabilities to metallic lithium and wide electrochemical window. Single or co-doped LLZO with Ga, Al, Nb were prepared by conventional solid state reaction and lithium ion conduction properties were investigated through electrochemical impedance spectroscopy in the temperature range of 248-318K. Among the doped compositions, Ga doped single phase cubic LLZO shows the highest ionic conductivity of 1.49×10 S/cm at room temperature and activation energy of 0.27eV. All single or co-doped LLZO samples exhibit low electronic conduction which are 4 to 5 orders of magnitude lower than their corresponding ionic conductivities. Ga-doped garnet LLZO of high ionic conductivity and negligible electronic conduction makes it a superior solid electrolyte for all-solid-state Li metal batteries.

Bibliographic Details

George Xing; Haoyu Zhu; Anna Zhuang; Fei Meng; Raymond Jiang; Yongchun Tang; Shuguang Chen; Guanhua Chen

Elsevier BV

Multidisciplinary; Keywords: Cubic phase; Garnet; LLZO; Li-ion; solid electrolyte

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