Aryl/Hetero-Aryl Tosylates as Coupling Partners in Metal Mediated Suzuki and Hiyama Cross-Coupling Reactions in Ionic Liquids: Facile Synthesis of Biaryls/Heterobiaryls
SSRN, ISSN: 1556-5068
2024
- 115Usage
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Example: if you select the 1-year option for an article published in 2019 and a metric category shows 90%, that means that the article or review is performing better than 90% of the other articles/reviews published in that journal in 2019. If you select the 3-year option for the same article published in 2019 and the metric category shows 90%, that means that the article or review is performing better than 90% of the other articles/reviews published in that journal in 2019, 2018 and 2017.
Citation Benchmarking is provided by Scopus and SciVal and is different from the metrics context provided by PlumX Metrics.
Article Description
Diverse libraries of biaryls/heterobiaryls were synthesized by aryl/hetero-aryl tosylates as coupling partners in the ligand-free, Ni-catalyzed Suzuki coupling reaction and Pd-catalysed Hiyama cross-coupling reaction in ionic liquids (ILs) as green solvent. In this method easily available and economically viable Tosylates were coupled with readily available boronic acids and phenyltriethoxysilanes in Suzuki and Hiyama cross-coupling respectively to yield the corresponding biaryls/heterobiaryls. Mild reaction condition(s), easy workup, moderate to excellent yield of the isolated pure products, wide substrate scope, and recycling/reuse of the ILs are the advantages of this method over the other reported methods.
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