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Innovative Zr-Mof/Mxene Composite for Enhanced Photothermal Catalytic Co2 Reduction in Atmospheric and Industrial Flue Gas Streams

SSRN, ISSN: 1556-5068
2024
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    105

Article Description

In this study, a novel composite was engineered by integrating Zr-MOF (NH2-UIO-66) with MXene layers through electrostatic self-assembly. Under simulated sunlight and at 80°C, this composite material achieved nearly complete conversion of low-concentration atmospheric CO2 to CO and CH4 without additional sacrificial agents or alkaline absorption liquids, marking one of the few reports demonstrating near-complete reduction of low-concentration CO2 directly from the air. For high-concentration CO2 in industrial flue gas, the composite utilized residual heat at 80°C without additional energy input, exhibiting excellent CO2 reduction efficiency with CO and CH4 production rates of 127 μmol·g-1·h-1 and 330 μmol·g-1·h-1, respectively, resulting in a total production rate 4.76 times higher than that in the air. Compared to most reports on thermocatalytic CO2 reduction (>300oC), this material shows significant advantages below 100oC. The performance improvement is attributed to the introduction of Zr-MOF, which provides additional active sites and reduces activation energy. Additionally, the localized surface plasmon resonance (LSPR) effect of MXene facilitates the migration of thermal charge carriers to Zr4+ sites within the MOF. Density Functional Theory (DFT) calculations validate these findings. Overall, Zr-MOF/MXene composite holds potential for reducing CO2 in air and industrial settings, advancing energy conversion and environmental management.

Bibliographic Details

Yang Meng; Feng Yue; Shuo Zhang; Lingji Zhang; Mengke Shi; Yongpeng Ma; Xiaojing Zhang; Hongzhong Zhang; Cong Li; Mario Berrettoni

Elsevier BV

Multidisciplinary; Zr-MOF/MXene; photothermal catalytic; CO2 Reduction; atmosphere; industrial emissions

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