Spectral lineshapes of collision-induced absorption (CIA) using isotropic intermolecular potential for N-CH
Journal of Computational Methods in Sciences and Engineering, ISSN: 1472-7978, Vol: 21, Issue: 4, Page: 1063-1078
2021
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Article Description
Quantum mechanical lineshapes of collision-induced absorption (CIA) at different temperatures are computed for gaseous mixtures of molecular nitrogen and methane using theoretical values for the induced dipole moments and intermolecular potential as input. Comparison with theoretical absorption spectra shows satisfactory agreement. An empirical model of the dipole moment which reproduces the experimental spectra and the first three spectral moments more closely than the fundamental theory, is also presented. Good agreement between computed and experimental absorption lineshapes is obtained when a potential model which is constructed from the thermophysical and transport properties is used.
Bibliographic Details
http://www.scopus.com/inward/record.url?partnerID=HzOxMe3b&scp=85116439447&origin=inward; http://dx.doi.org/10.3233/jcm-210049; https://journals.sagepub.com/doi/full/10.3233/JCM-210049; https://dx.doi.org/10.3233/jcm-210049; https://content.iospress.com:443/articles/journal-of-computational-methods-in-sciences-and-engineering/jcm210049
SAGE Publications
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