Quantifying biogenic versus detrital carbonates on marine shelf: An isotopic approach

The terrigenous sedimentary budget of passive margins, records variations in past sedimentary fluxes, and thus can be used to infer past variations of Earth surface deformation processes or climate change. Accurate estimates of sediment fluxes over various times and spatial scales are therefore crucial. Traditionally, offshore sediment volume determination only considers siliciclastic accumulation, the carbonate fraction (i.e., CaCO) being considered only as in situ production. Here we propose a new geochemical methodology to decipher and quantify the number of detrital carbonates in comparison to in situ produced biogenic carbonates. This isotopic approach enables considering the export of detrital carbonates and investigating its effect on sediment budgets. This study, located in the Gulf of Lion, is based on a 300 m long sediment borehole located near the shelf break and covering the last 500 000 years (i.e., five glacial-interglacial periods). Strontium isotope (Sr/Sr) of carbonate fractions (0.70809 to 0.70858) are significantly less radiogenic than modern seawater (i.e., 0.7092) and show fluctuations in agreement with stratigraphic and climatic variations. These results suggest an unsuspected high export of detrital carbonates from the catchment area during both glacial (between 55 and 85% of the sedimentary carbonate fraction) and interglacial (between 30 and 50%) conditions. Thus, not only do detrital carbonate fluxes need to be factored into sediment flux calculations, but these results also suggest that detrital carbonate components could potentially have a strong influence on bulk carbonate Sr/Sr ratios when not obtained from micro drilled biogenic carbonates, such as the entirety of the Precambrian Sr chemostratigraphic record.