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The structure and property of two different metal-organic frameworks based on N/O-donor mixed ligands

Crystals, ISSN: 2073-4352, Vol: 11, Issue: 9
2021
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Article Description

Two different metal-organic frameworks (MOFs) [Cd(AZN)(HAZN)(btc)(Hbtc)·4HO]·2HO (1), and [Zn (AZN) (btc)·4HO] (2) were synthesized by the reactions of different metal salts with mixed ligands of 1-(4-(1H-imidazol-5-yl)phenyl)-1H-1,2,4-triazole (AZN) and trimesic acid (Hbtc). The different metal centers in the reaction condition have important impact on the resulting structures of MOFs 1 and 2. Compound 1 is a one-dimensional (1D) chain structure, while 2 features a threedimensional (3D) framework with 3-fold interpenetration topology of Point (Schläfli) symbol of (6·8) (6). Furthermore, the luminescent properties have been studied for MOFs 1 and 2.

Bibliographic Details

Zhiqiang Lu; Yanzhi Li; Yi Ru; Shujian Yang; Chu Hao; Mengke Zuo; Rongkai Jiao; Hui Yao

MDPI AG

Chemical Engineering; Materials Science; Physics and Astronomy; Chemistry

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