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Hematite Exsolutions in Corundum from Cenozoic Basalts in Changle, Shandong Province, China: Crystallographic Orientation Relationships and Interface Characters

Crystals, ISSN: 2073-4352, Vol: 12, Issue: 7
2022
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Article Description

Here, we present well‐oriented hematite exsolutions in corundum megacrysts from Cenozoic basalt in China. Crystallographic orientation relationships (CORs) and the interface characters between the hematite exsolutions and the corundum host were analyzed by electron backscatter diffraction (EBSD) and high‐resolution transmission electron microscope (HRTEM), respectively. The CORs and the regular interface confirm the exsolution and the exsolution was formed under depressurization based on the crystal chemistry theory. There are three groups of exsolutions inter-sected with ~60°. Two groups of the exsolutions have the same orientation with the host and the other group is twinned to those two groups. Focused ion beam (FIB) for HRTEM foil preparation was carried out. HRTEM photographs show that there are periodic coherency units at (0001) inter-face. The measured unit lengths are 6.71–6.72 nm, which are in good agreement with every 17‐ projection projection D2)2). Based on the results, the possibility is that at the interface, the hema-tite‐corundum phases tend to modulate to achieve the maximum coherency in the geological pro-cess during exsolution. This research is helpful to understand the interface characters between the exsolution and host.

Bibliographic Details

Qianyi Zhao; Shanrong Zhao; Chang Xu

MDPI AG

Chemical Engineering; Materials Science; Physics and Astronomy; Chemistry

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