Fluid-fluid interfaces of multi-component mixtures in local equilibrium
Entropy, ISSN: 1099-4300, Vol: 20, Issue: 4
2018
- 7Citations
- 8Captures
- 1Mentions
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Example: if you select the 1-year option for an article published in 2019 and a metric category shows 90%, that means that the article or review is performing better than 90% of the other articles/reviews published in that journal in 2019. If you select the 3-year option for the same article published in 2019 and the metric category shows 90%, that means that the article or review is performing better than 90% of the other articles/reviews published in that journal in 2019, 2018 and 2017.
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- Citations7
- Citation Indexes7
- CrossRef7
- Captures8
- Readers8
- Mentions1
- Blog Mentions1
- 1
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Entropy, Vol. 20, Pages 250: Fluid-Fluid Interfaces of Multi-Component Mixtures in Local Equilibrium
Entropy, Vol. 20, Pages 250: Fluid-Fluid Interfaces of Multi-Component Mixtures in Local Equilibrium Entropy doi: 10.3390/e20040250 Authors: Dick Bedeaux Signe Kjelstrup We derive in a
Article Description
We derive in a new way that the intensive properties of a fluid-fluid Gibbs interface are independent of the location of the dividing surface. When the system is out of global equilibrium, this finding is not trivial: In a one-component fluid, it can be used to obtain the interface temperature from the surface tension. In other words, the surface equation of state can serve as a thermometer for the liquid-vapor interface in a one-component fluid. In a multi-component fluid, one needs the surface tension and the relative adsorptions to obtain the interface temperature and chemical potentials. A consistent set of thermodynamic properties of multi-component surfaces are presented. They can be used to construct fluid-fluid boundary conditions during transport. These boundary conditions have a bearing on all thermodynamic modeling on transport related to phase transitions.
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