Structural diversity of six coordination polymers based on the designed X-shaped ligand 1,1,1,1-tetrakis[(3-pyridiniourea)methyl]methane
Molecules, ISSN: 1420-3049, Vol: 23, Issue: 9
2018
- 8Citations
- 1Captures
- 1Mentions
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Metrics Details
- Citations8
- Citation Indexes8
- CrossRef7
- Captures1
- Readers1
- Mentions1
- Blog Mentions1
- Blog1
Most Recent Blog
Molecules, Vol. 23, Pages 2292: Structural Diversity of Six Coordination Polymers Based on the Designed X-Shaped Ligand 1,1,1,1-Tetrakis[(3-pyridiniourea)methyl]methane
Molecules, Vol. 23, Pages 2292: Structural Diversity of Six Coordination Polymers Based on the Designed X-Shaped Ligand 1,1,1,1-Tetrakis[(3-pyridiniourea)methyl]methane Molecules doi: 10.3390/molecules23092292 Authors: Qi-Long Zhang Qing
Article Description
In this study, six coordination polymers (CPs), {[Ag(L)(CFSO)]·CFSO·2HO·DMF} (1), {[Ag(L)]·SbF·4DMF·HO} (2), {[Zn(L)(I)]·3.75HO} (3), {[Cd(L)(I)(HO)(DMF)]·4HO·3DMF} (4), {[Hg(L)(I)]·HO·4DMF} (5) and {[Hg(L)(Cl)]·2HO·3DMF} (6), were obtained based on the designed X-shaped urea-based ligand. X-ray single crystal diffraction analysis revealed that complex 1 displayed a 3D (3,4)-connected {6·8}{6·8}-tcj net. Complex 2 featured a 2D 4-connected {4·6} sheet. Complexes 3 and 5 exhibited a 1D polymeric loop chain. Complex 4 displayed a 1D polymeric fishbone chain. Complex 6 showed a 2D 4-connected {4·6}-sql sheet. Structural comparison revealed that not only the metal ions, but also the anions played crucial roles in the control of final structures.
Bibliographic Details
MDPI AG
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