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π-Stacked polymer consisting of a Pseudo-meta-[2.2]paracyclophane skeleton

Polymers, ISSN: 2073-4360, Vol: 10, Issue: 10
2018
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Article Description

A novel π-stacked polymer based on a pseudo-meta-linked [2.2]paracyclophane moieties was synthesized by Sonogashira-Hagihara coupling. The UV-vis absorption spectra of the synthesized polymer and model compounds revealed an extension of the conjugation length owing to the through-space conjugation. The optical properties of the π-stacked dimer with the pseudo-meta-linked [2.2]paracyclophane unitwere comparedwith those of the corresponding dimerswith the pseudo-ortho- and pseudo-para-linked [2.2]paracyclophane units.

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