Comparative analysis of fluorinated anions for polypyrrole linear actuator electrolytes
Polymers, ISSN: 2073-4360, Vol: 11, Issue: 5
2019
- 26Citations
- 55Captures
- 1Mentions
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- Citations26
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- 26
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- Captures55
- Readers55
- 55
- Mentions1
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Polymers, Vol. 11, Pages 849: Comparative Analysis of Fluorinated Anions for Polypyrrole Linear Actuator Electrolytes
Polymers, Vol. 11, Pages 849: Comparative Analysis of Fluorinated Anions for Polypyrrole Linear Actuator Electrolytes Polymers doi: 10.3390/polym11050849 Authors: Nguyen Quang Khuyen Zane Zondaka Madis
Article Description
Either as salts or room temperature ionic liquids, fluorinated anion-based electrolytes have been a common choice for ionic electroactive polymer actuators, both linear and bending. In the present work, propylene carbonate solutions of four electrolytes of the three hugely popular anions-triflouromethanesulfonate, bis(trifluoromethane)sulfonimide, and hexafluorophosphatewere compared and evaluated in polypyrrole linear actuators. The actuation direction, the characteristics-performance relations influence the behavior of the actuators. Isotonic Electro-chemo-mechanical deformation (ECMD)measurementswere performed to study the response of the PPy/DBS samples. The highest strain for pristine PPy/DBS linear actuatorswas found in range of 21%for LiTFSI,while TBAPF had the least cation involvement, suggesting the potential for application in durable and controllable actuators. Interesting cation effects on the actuation of the same anions (CFSO -)were also observed.
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