Asymmetric synthesis of cryptofolione and determination of its absolute configuration
Heterocycles, ISSN: 0385-5414, Vol: 66, Issue: 1, Page: 187-194
2005
- 13Citations
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Article Description
Two possible stereoisomers of cryptofolione, isolated from the Cryptocarya species in South Africa and Brazil, were synthesized in an enantioselective manner by using asymmetric hetero Diels-Alder reaction as the key steps. Comparative evaluation of the H NMR, C NMR, CD spectra, and specific rotation of the synthetic compounds with those reported in the literature was performed to establish the absolute configuration of cryptofolione to be [6R,10S,12R]. © 2005 The Japan Institute of Heterocyclic Chemistry.
Bibliographic Details
http://www.scopus.com/inward/record.url?partnerID=HzOxMe3b&scp=33646866361&origin=inward; http://dx.doi.org/10.3987/com-05-s(k)73; https://triggered.stanford.clockss.org/ServeContent?doi=10.3987%2Fcom-05-s%28k%2973; http://dx.doi.org/10.3987/com-05-s%28k%2973; https://dx.doi.org/10.3987/com-05-s%28k%2973; https://chooser.crossref.org/?doi=10.3987%2FCOM-05-S%28K%2973
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