Anionic copolymerization of acrylonitrile with ethyl acrylate under the action of the initiating system of 1,4-diazabicyclo[2.2.2]octane – ethylene oxide
Key Engineering Materials, ISSN: 1662-9795, Vol: 899 KEM, Page: 226-231
2021
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Conference Paper Description
It was found, studying acrylonitrile copolymerization with ethyl acrylate in dimethyl sulfoxide under the action of anionic initiating system of 1,4-diazabicyclo[2.2.2]octane – ethylene oxide, that the obtained copolymers have a branched structure. An increase in the molar fraction of ethyl acrylate in the reaction medium leads to a decrease in the initial rate of acrylonitrile polymerization. Thermal behavior of copolymer samples was investigated; it was found that ethyl acrylate, being introduced into the polyacrylonitrile structure, both reduces thermal effects related to the reactions taking place during heat treatment of copolymers, and increases the half-width of the heat release peak.
Bibliographic Details
Trans Tech Publications, Ltd.
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