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Inclusion of a dithiadiazolyl radical in a seemingly non-porous solid

Chemical Communications, ISSN: 1364-548X, Vol: 53, Issue: 82, Page: 11310-11313
2017
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Article Description

Inclusion of the dithiadiazolyl radical PhCNSSN into the dynamically porous metallocycle [Cu(L1)Cl], where L1 is the bidentate ligand 1,3-bis(imidazol-1-ylmethyl)-2,4,6-trimethylbenzene, has been achieved by gas phase diffusion. Single crystal X-ray diffraction, powder X-ray diffraction, UV-visible spectroscopy, EPR and SQUID magnetometry studies confirm inclusion of the radical into this seemingly non-porous material, and illustrate the antiferromagnetic coupling between the paramagnetic host and guest species. The radical guest is readily released by heating or by the addition of solvent (CHCl).

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