Cyclocondensation Reactions of a Bifunctional Monomer Bearing a Nucleophilic Hydrazine and Electrophilic Ketoester Pair
SSRN, ISSN: 1556-5068
2022
- 584Usage
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Example: if you select the 1-year option for an article published in 2019 and a metric category shows 90%, that means that the article or review is performing better than 90% of the other articles/reviews published in that journal in 2019. If you select the 3-year option for the same article published in 2019 and the metric category shows 90%, that means that the article or review is performing better than 90% of the other articles/reviews published in that journal in 2019, 2018 and 2017.
Citation Benchmarking is provided by Scopus and SciVal and is different from the metrics context provided by PlumX Metrics.
Article Description
An approach to combine monomer units forming heterocyclic linkages is described. A bifunctional monomer bearing a nucleophilic hydrazine and electrophilic ketoester pair was designed and synthesized. The monomer was employed to construct oligomeric products containing pyridazinone linkages via cyclocondensation reactions. The cyclocondensation oligomerization yielded up to pentamers including macrocycles. Regiochemical studies with model compounds revealed that the cyclocondensation occurred via a hydrazone intermediate when conducted under acidic conditions.
Bibliographic Details
http://www.scopus.com/inward/record.url?partnerID=HzOxMe3b&scp=85177976281&origin=inward; http://dx.doi.org/10.2139/ssrn.4240820; https://www.ssrn.com/abstract=4240820; https://dx.doi.org/10.2139/ssrn.4240820; https://papers.ssrn.com/sol3/papers.cfm?abstract_id=4240820; https://ssrn.com/abstract=4240820
Elsevier BV
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